Dew
PDF
Everybody knows or has experienced what is dew, when soil and plants are wet in the morning of clear and calm nights or when water flows on the walls and windows of kitchen and bathrooms. But where dew comes from? Its origin has long been a mystery. From alchemist to scientists many savants have elaborated more or less rigorous theories. It is only in the middle of the XXth century that a comprehensive interpretation of dew was elaborated. Dew is beneficial to plants and animals, but can it be used by humans as a new source of water? How to harvest dew? What are the chemical and biological qualities of dew? Is it potable? All these questions are answered in this article.
1. Dew: a long history in mysteries
Everybody knows what dew is. But where dew comes from?
Natural dew is a ubiquitous phenomenon, already noted in the oldest literature. For instance, in the Hebraic bible (Ecclesiaste 1:2) the famous words “All is vanity” correspond actually, in Hebrew, to the word dew, highlighting dew beauty and brightness but also dew ephemeral nature. In Japanese culture, many Haikus have been written with dew. These are some of the many examples of dew as used in art and literature.
In contrast to natural dew, which essentially forms outside, there is another dew which is found on the cold walls of caves and humid rooms such as kitchens, bathrooms and laundry rooms. The difference comes from the origin of cooling: natural dew originates from a radiative exchange with the cold sky and is efficient only outside while the other “dew” proceeds from contact cooling. It is the same “dew” as the “breath figures” that form on a glass when you breathe on it.
People have indeed been long fascinated by dew. They could not understand how water could cover the ground and plants at night even though the sky was clear. A major step has been reached with Leroy (1751) [1] who understood that water can be dissolved in air like sugar in water, with the highest the temperature, the largest the dissolution. Then cooling warm humid air leads inevitably to extract liquid water, precisely at the dew point temperature. Wells (1866) [2]carried out the first comprehensive study of dew condensation but did not explain the reason of nightly cooling. The latter process has been highlighted by Jamin (1879) [3] with radiative cooling. It is only much later that Monteith (1957) [4] formalized dew formation by using a full energy balance.
1.1. Dew, a new source of water?
Figure 1. Dew water collection by alchemists [Source : adapted from Mutus Liber, 1677 [1]].
The first documented human use of dew water is perhaps dew collection by alchemists, noted in the book Mutus Liber(1677) [5], called the “Mute Book” because it is composed only of drawings. In Figure 1 dew is collected at night (noted by the moon) on horizontal sheets stretched over sticks. Water is then recovered by squeezing the sheets on a basin. The next documented attempts are concerned with massive dew condensers, working on temperature inertia, and then corresponding to non-radiative dew type. Such condensers are described below in Section 2.3.
Radiative condensers have been the object of several studies since the trials of massive condensers. Many areas of science and technology are indeed concerned in the process of dew condensation and collection, allowing many ideas for improvement to be tried: atmospheric optics and physics, radiative, conductive and convective heat exchanges, hydrodynamics, chemistry, biology. Simple large planar condensers have been erected (Figure 2a), more sophisticated dew plants, made of ridges (Figure 2b), have been constructed . Many other kind of radiative dew condensers (conical-like, origami, etc.) were designed to increase cooling and dew drop collection. They are presented in the book Dew Water (2018) [6].
1.2. Dew on plants
Dew condensing on plants can bring moisture and helps to fight again drought periods. Plants can absorb water through their leaves to compensate for depleted water tables and survive drought. More complex scenarii can, however, help plants. For instance, the biological soil crust (Read : Lichens, surprising pioneering organisms) can retain and use water from dew to increase the concentration of dissolved organic nitrogen, associated with the fixation of atmospheric N2 by cyanobacteria and cyanolichens. Dew can also prolong seedlings life under drought stress conditions.
On the other hand, dew, in addition to high relative humidity, can influence the occurrence of plant disease with moisture on plant surfaces promoting the development of pathogenic germs and increasing disease frequency in many crops. Cryptogrammic diseases are observed on grass, banana and potatoes leaves. However, the development of such fungi can be sometimes beneficial. This is the case for the elaboration of some sweet wine. For instance, the famous Sauternes vineyard “noble rot” is known to come from the action of Botrytis Cinerea fungus.
2. How to collect dew?
2.1. Dew yield
According to the preceding Sections, the collecting surface has to reach the dew point to initiate condensation. The surface will be thus below the air temperature and heat losses, triggered by wind, will be present. An energy balance can be written where, in the steady state, the radiative cooling power R (in W. m-2) (see Focus 1) counterbalances heating by air losses, proportional to the difference between air temperature and dew point temperature , and heating by the release of latent heat L (Read : Pressure, temperature and heat), such as
Here S (in m2) is the condensing surface and a (in W.m-2.K-1) is the heat transfer coefficient [7], which increases with wind speed. Condensed mass is m (kg), related to condensed volume V (m3) by the water volumic mass (kg.m3) through . Time is denoted by t (in s). The quantity L is the latent heat (in J.kg-1). One can readily deduce the condensed water volume per surface area, classically expressed in litres per square meter, or mm. For the ideal case where the atmosphere has a large relative humidity, giving , the maximum yield, only limited by the available power (see Figure 1 of Focus 1 for its value according to air temperature and humidity) is on the order of 1 mm per night.
2.2. Radiative dew collectors
The oldest mentioned dew condenser to our knowledge is reported in the “Dumb book” for Alchemists (Mutus liber, 1677 [5]) where horizontal cloths are fixed to sticks and then soared by hand (Figure 1). In dew collectors one has to consider two processes, dew condensation and drop collection. Both processes are of importance. According to the previous Section, the dew yield increases with radiative power and decreases with wind speed. In Focus 1 details on radiative cooling are given. It is shown that the cooling power is proportional to the condensing surface emissivity (or absorptivity) – the ability of a material to emit and absorb light – and to the difference of the atmosphere emissivity with 1. It thus comes out that, under given conditions of atmosphere emissivity and wind speed, the dew yield can be improved by (i) lowering atmosphere emissivity, (ii) increasing condensing surface emissivity, (iii) decreasing heat exchange with surrounding air and (iv) increasing the efficiency of the dew drop collection.
One can lower the atmosphere emissivity (point (i)) by considering a condenser design that uses only the near zenith angle of the atmosphere, where atmosphere emissivity is the lowest (see Figure 2 of Focus 1). Surface emissivity (point (ii)), if not too low, is that of water and cannot be changed. However, having a substrate of low emissivity and thus absorptivity only for the solar radiation spectrum permit better cooling of the condenser at the end of the day and in the morning, making longer the duration of dew condensation.
Concerning drop collection, point (iv), passively harvesting by gravity the weak dew events without scraping is indeed a major challenge. There is a basic contradiction between having a surface facing the zenith and also having the maximum surface tilt angle for easy drop sliding by gravity. It has been shown [9] that a surface tilt angle in the range 20° – 30° gives the best results.
2.3. Massive dew collectors
Soviet scientists [14], just like their counterparts in France, Knapen [17], and Chaptal [18], which had heard of the Zibold condenser, got interested again in the collection of water of dew by this technique of massive condensers. However, although Knapen constructed a quite sophisticated condenser (Figure 5c) the yields were always found very weak because the inertia was concerned on days or weeks duration, not seasons. Such small yields simply reflect the fact that the mean temperature of the massive condensers goes only rarely below the air dew point temperature. As a matter of fact, Chaptal deconstructed its condensing pyramid to “not induce in errors the future generations”. Although deceiving, the massive condenser yields could, however, be improved by carrying out new studies taking e.g. into account the underground temperature, as for Canadian wells where inertia gives much longer condensation times, and using more sophisticated technologies (Figure 5d).
2.4. Active dew collectors
Cooling can be also ensured by an active device similar to those used in the fridges. Energy, most often electric, has to be provided. Commercial systems do exist (see e.g. www.candew.ca), the yield is on order 0.5 -1 kWh/L depending on the atmospheric conditions. However they remain quite expensive.
3. Can dew water be drunk? Chemical and biological quality
Dew water is the result of water vapour condensation. One might think it is as pure as distilled water. However, dew forms on a substrate in an open area. The interactions dew-atmosphere and dew-substrate will then give to dew water its specific chemical and biological properties.
3.1. Chemical composition
Dewcan interact with its substrate by partially dissolving it (e.g. zinc substrate [19]). Dew also interacts with the atmosphere. The latter is characterized by gases, which can be absorbed by water, and aerosols, which deposit on the substrate, acting as nucleation sites11 for dew condensation and reacting with the condensed water. Then three steps govern dew chemical composition: (i) Formation of dew on dry deposition solids, (ii) dissolution of the soluble portion of the dry deposition by dew water, and (iii) sorption of gases into the dew solution.
Carbon dioxide plays a special role in the formation of acidity in the liquid phase because of its high and constant concentration. An important pathway in alkalinity (carbonate) formation goes via condensation nuclei (nucleation11 and droplet formation) as well as aerosol scavenging. The ability to capture particulates, e.g. CaCO3 from buildings or carbon particles from diesel cars, is very relevant for dew chemical composition and is strong at the beginning of the condensation process and weakened at the end. The acidity from dissolved CO2, SO2, and NOx (x = 1, 2) is mostly neutralized by Mg2+, Ca2+ and NH4+; sometimes a slight alkaline character is observed in dew samples. Dew events with the higher ionic concentration occur following long periods without rain. One has to note that the high concentrations in dew water of SO2 (giving sulfuric acid), NO (nitreous acid) and NO2 (nitric acid) is mostly of anthropogenic origin, in other words, coming from the atmospheric pollution by human activities (industry, agriculture, transportation).
Uptake of high soluble gases on atmospheric water is very fast. It will then not be affected by the short time of dew formation. When in equilibrium with atmospheric CO2, the HCO3– concentration is an exponential function of the pH-value. When the pH solutions is higher than 6.35 (pKa1 of H2CO3), the concentration [HCO3–] can become important. But samples of the atmospheric multiphase system are most probably not in equilibrium with atmospheric CO2 due to complex chemical compositions, microphysical processes and heterogeneous interactions, then the [HCO3–] concentration can only be obtained by analytical estimation and not deriving Henry’s law [20].
Dew water composition is thus a function of both long range convected atmosphere and locally produced gas and aerosols. The source of anthropogenic and natural species can be found by different techniques, including air mass trajectory and stable isotope analyses. In general, regional urban pollutions have significant influence on dew water chemistry. In Table 1 are shown for sake of comparison the mean composition of dew and a low mineralized spring water (Mt Roucous); they compare relatively well.
Table 1. Chemical composition of dew measured in Bordeaux (annual mean, from Beysens et al., 2006 [21]). It compares well with Mont Roucous spring water, which exhibits a low concentration of dissolved solids
Measurement | Dew | Mt Roucous |
pH | 5.88 | 6.0 |
Conductivity
(µS/cm) |
29 (25oC) | 25 (20°C) |
Na+, mg/l | 2.85 | 2.80 |
K+, mg/l | 0.25 | 0.40 |
Ca++, mg/l | 0.35 | 1.20 |
Mg++, mg/l | 0.35 | 0.20 |
Cl–, mg/l | 4.8 | 3.20 |
SO4—, mg/l | 2.5 | 3.30 |
NO3–, mg/l | 0.5 | 2.30
|
NO2–, mg/l | <0.01 | |
Dry residue
(180°C), mg/l |
10.3
|
19.0
|
3.2. Biological features
Biological contamination of substrates comes via direct depositions by insects, birds and small mammals, decay of organic debris, and atmospheric deposition of airborne micro-organisms. Contamination is generally inevitable because dew condensers are positioned in an open environment. The biological effects associated to dew are of different nature depending whether the substrate is alive, like plants, or inert.
The biological quality of dew water collected on inert substrates depends whether the microorganisms deposited on the substrate are harmless or not to human. Analyses are generally concerned with (i) aerobic bacteria as measured by colony-forming units [22] at 22 °C and (ii) at 36 °C. The first set (i) corresponds generally to harmless, vegetal microorganisms coming from the surrounding. The second set (ii) is brought mainly by insects, bird waste, mammals and human contamination. More specific investigation about human microorganisms (Enterococus, Coliforms) have also been carried out.
Microorganism contamination is fortunately limited by ultraviolet sun irradiation of dew condenser surfaces [21]. Nevertheless, the biological analysis of dew and rain shows that the World Health Organization limits can be often exceeded. To become potable, disinfection, such as e.g. with chlorination, is therefore recommended.
4. Biological sterilization by dew condensation
The fact that condensation can occur everywhere on a substrate, even in areas of difficult access, can be used to disinfect medical chambers and instruments (e.g. endoscopes) provided a sterilizing or antiseptic agent is added in the vapour (Marcos-Martin et al., 1996 [23]). Such additives are chemical vapours (e.g. ethylene oxide, formaldehyde, chlorine dioxide or hydrogen peroxide). Sterilization is indeed the result of complex chemical reactions involving alkylation or oxidation and reduction reactions, which produce free radicals such as the hydroxyl radical, one of the most powerful oxidants.
5. Messages to remember
- Dew is often misleadingly viewed as a form of precipitation and confounded with fog. Natural dew has also to be differentiated from water condensation on the cold walls of caves and humid room where cooling comes from the wall thermal inertia.
- Dew yield is primarily limited by the available cooling energy, which practically does not exceed about 100 W.m-2, leading to a theoretical maximum yield on order of 1 L.m-2 per night.
- Natural dew can give a non-negligible contribution to the water budget and additional water to plants and desert animals, not only in arid and semi-arid areas, but also during dry summer seasons where drought can occur for more than weeks or months.
- Radiative dew harvesting for human use has recently come to near achievement status due to better understanding of associated physics and thermodynamics, the combination of new materials and condenser shapes, conical, pyramidal, origami.
- The chemical properties of dew water come from the chemicals (gases and aerosols) present in the atmosphere in the vicinity of the condenser. It can also be connected to interaction with the condensing substrate itself.
- Biological contamination of dew water originates from spores and bacteria of vegetal, animal and human origin. It is of atmospheric origin or coming from direct deposition by insects, birds, small mammals, human and airborne microbes. Such contamination is generally inevitable because dew condensers are placed in an open environment. It means that dew water should be disinfected for drinking use.
- Sterilization by dew. In a similar way of dew condensation, but indoor, sterilization of medical instruments and hospital rooms can be carried out by condensing water with specific sterilizing elements.
Notes and references
Cover Image. [Source : https://pixabay.com/ – Royalty free image]
[1] LEROY, C. (1751). Mémoire sur l’Élévation et la Suspension de l’Eau dans l’Air, et sur la Rosée. (Dissertation on the Elevation and the Suspension of Water in the Air, and on Dew). Mémoires de l’Acad. Roy. des Sci. 481–518.
[2] WELLS, W. C. (1866). An Essay on Dew and Several Appearances Connected with it. London : Longmans, Green, Reader and Dyer.
[3] JAMIN, J. (1879). La rosée, son histoire et son rôle. Revue des Deux Mondes 31, 324–345.
[4] MONTEITH, J. L. (1957). Dew. Q. J. R. Meteorol. Soc. 83, 322–341.
[5] ALTUS, SAULAT J. (1677). Mutus Liber. La Rochelle : Pierre Savouret.
[6] BEYSENS, D. (2018). Dew water. Gistrup : Rivers Publisher.
[7] The HEAT TRANSFER COEFFICIENT is the coefficient which relates the surfacic heat flux and the temperature difference at the origin of the flux.
[8] SHARAN, G., ROY, A. K., ROYON, L., MONGRUEL, A., BEYSENS, D. (2017). Dew plant for bottling water. J. Clean. Prod. 155 (1), 83–92.
[9] BEYSENS, D., MILIMOUK, I., NIKOLAYEV, V., MUSELLI, M., MARCILLAT,J. (2003). Using radiative cooling to condense atmospheric vapour: a study to improve water yield, J of Hydrology 276 (1-4 ), 1-11.
[10] BEYSENS, D. BROGGINI, F., MILIMOUK-MELNYTCHOUK, I., OUAZZANI, J., TIXIER, N. (2013). New Architectural Forms to Enhance Dew Collection. Chemical Engineering Transactions 34, 79-84.
[11] NUCLEATION is the first step of formation of a new phase (here liquid) in a given phase (here vapour). It is facilitated by geometric or chemical defects.
[12] OPUR. Available at www.opur.fr
[13] NIKOLAYEV, V., BEYSENS, D., GIODA, A., MILIMOUKA, I., KATIUSHIN, E.,MOREL, J. (1996). Water recovery from dew. J. Hydrol. 182, 19–35.
[14] MYLYMUK-MELNYTCHOUK, I., BEYSENS, D. (2016). Puits aériens : mythes et réalités ou Travaux russes & soviétiques sur la production d’eau à partir de l’air. Sarrebruck : Editions Universitaires Européennes.
[15] TOUGARINOV, V.V. (1935). Condensation of atmospheric water vapour. Anonymous, 1935. Stenograph of the proceedings of the 1st Conf. on the condensation of the atmospherical water vapour (Aerial well) (1931). Moscow-Leningrad: Cuegms (in Russia). Traduction (French): MYLYMUK-MELNYTCHOUK, I., BEYSENS, D. (2016). Puits aériens : mythes et réalités ou Travaux russes & soviétiques sur la production d’eau à partir de l’air. Sarrebruck : Editions Universitaires Européennes.
[16] TOTCHILOV, V.I. (1938). Condensers of Feodosia and the conditions of condensation in the surroundings. Soviet Water Works and Sanitary Engineering 1, 61-67 (in Russian).
[17] KNAPEN, M. A. (1929). Dispositif intérieur du puits aérien Knapen. (Interior device of the Knapen aerial well). Extrait des mémoires de la société des Ingénieurs civils de France. (Bull. Jan–Feb). Imprimerie Chaix, Paris..
[18] CHAPTAL, L. (1932). La captation de la vapeur d’eau atmosphérique. (Harvesting atmospheric water vapour). La Nature 60, 449–454.
[19] LEKOUCH, I., MUSELLI, M., KABBACHI, B., OUAZZANI, J., MELNYTCHOUK-MILIMOUK, I., BEYSENS, D. (2011). La rosée, le brouillard et la pluie comme sources supplémentaires d’eau dans le sud-ouest du Maroc. Energy 36 (4), 2257-2265.
[20] HENRY’S LAW states that the amount of dissolved gas in a liquid is proportional to its partial pressure above the liquid.
[21] BEYSENS, D., OHAYON, C., MUSELLI, M., CLUS, O. (2006). Chemical and biological characteristics of dew and rain water in an urban coastal area (Bordeaux, France). Atmospheric Environment 40 (20), 3710–3723.
[22] COLONY-FORMING UNIT is a unit used in microbiology to quantify the number of micro-organisms present in a given medium. After having taken samples from the medium, cultures are made under specific conditions on a medium able to develop the micro-organisms that form colonies, which can be counted.
[23] MARCOS-MARTIN M.-A., BARDAT A., SCHMITTHAEUSLER R., BEYSENS D. (1996). Sterilization by vapour condensation. Pharm. Techn. Eur. 8, 24–32.
[24] ASP. Products. Available at https://www.asp.com/products
[25]Bioquell. Risk Reduction Solutions for Pharmaceutical, Life Sciences & Healthcare. Available at https://www.bioquell.com/life-sciences/our-technology-for-life-sciences/.
[26] RADIATION is the emission of energy by electromagnetic waves.
[27] STATES OF MOLECULAR EXCITATIONS: An excited state of an atom or a molecule is a quantum state with a higher energy than the minimum, ground state (that is, more energy than the absolute minimum). Excitations by e.g. the absorption of light (a photon) increase the energy level above a chosen starting point, the ground state or an already excited state. The return to a less excited state corresponds to the emission of a photon (light) whose wavelength depends on the difference in energy of the two states. For thermal excitation at room temperature, the range of energy corresponds to infra-red wavelengths
[28] THE ATMOSPHERIC BOUNDARY LAYER comprises the lowest part of the atmosphere extending from the ground). It is the place where ground and atmosphere exchange radiative, sensitive and latent heats (https://www.encyclopedie-environnement.org/physique/pression-temperature-et-chaleur/). It extends until where cumulus clouds form, which marks the commencement of the free atmosphere. In this layer many physical quantities (air flow velocity, temperature, humidity…) display rapid and turbulent fluctuations and vertical mixing is strong. The boundary layer thickness, h, can range from tens of meters to a few km and varies with time and can be expressed as where h is in km and Ta is the air temperature and Td the dew point temperature near the ground.
[29] BLISS R. A. (1961). Atmospheric radiation near the surface of the ground. Solar Energy 5 (3), 103–120
[30] BERGER, X., BATHIEBO, J. (2003). Directional spectral emissivities of clear skies. Renewable Energy 28 (12), 1925–1933.
[31] HOWELL, J.C., YIZHAQ, T., DRECHSLER, N., ZAMIR, Y., BEYSENS, D., SHAW, J.A. (2021). Generalized Nighttime Radiative Deficits. Journal of Hydrology 603 (B), 126971.
The Encyclopedia of the Environment by the Association des Encyclopédies de l'Environnement et de l'Énergie (www.a3e.fr), contractually linked to the University of Grenoble Alpes and Grenoble INP, and sponsored by the French Academy of Sciences.
To cite this article: BEYSENS Daniel (2022), Dew, Encyclopedia of the Environment, [online ISSN 2555-0950] url : https://www.encyclopedie-environnement.org/en/air-en/dew/.
The articles in the Encyclopedia of the Environment are made available under the terms of the Creative Commons BY-NC-SA license, which authorizes reproduction subject to: citing the source, not making commercial use of them, sharing identical initial conditions, reproducing at each reuse or distribution the mention of this Creative Commons BY-NC-SA license.